HCID 12361482, compound → HCID 10313957, compound

HRID 1728806Notes

Reaction equation

HRID 1728806 reaction equation
C[O:2][C:3](=O)[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].[H-].[Al+3].[Li+].[H-].[H-].[H-]>O1CCCC1>[CH2:11]([O:10][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=1[CH2:3][OH:2])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

Participants

4

Reactant 2

HCID 12361482HCID 12361482, compoundHCID 21226445Aluminium lithium hydride

Product 1

HCID 10313957HCID 10313957, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The title compound is prepared by the procedure of Example 19 using 20.0 g of product from Example 17, 200 ml of dry tetrahydrofuran and 6.53 g of lithium aluminum hydride. The reaction is stirred at room temperature for 60 hours. The product, 18.4 g, is obtained as colorless crystals.

Workup

  1. customThe product, 18.4 g, is obtained as colorless crystals

Sources & evidence

ORD record
ord-9430312633ac47ff81a464146e81e84c
Source dataset
uspto-grants-1994_07
Patent number
US05328921

Reaction notes

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