P-Xylene → HCID 19016928, compound

HRID 1728989Notes

Reaction equation

HRID 1728989 reaction equation
[CH3:1][C:2]1[CH:3]=[CH:4][C:5]([CH3:8])=[CH:6][CH:7]=1.[CH3:9][C:10]([CH3:17])=[CH:11][C:12](OCC)=[O:13].[F-]>>[CH3:9][C:10]1([CH3:17])[C:4]2[C:3](=[C:2]([CH3:1])[CH:7]=[CH:6][C:5]=2[CH3:8])[C:12](=[O:13])[CH2:11]1

Participants

4

Reactant 3

HCID 7809P-XyleneHCID 12516Ethyl 3,3-dimethylacrylateHCID 28179Fluoride Ion

Product 1

HCID 19016928HCID 19016928, compoundYield 95.6%

Procedure

10.6 g (100 mmol) of p-xylene (99% purity) and 14.4 g (112 mmol) of ethyl 3,3-dimethylacrylate were reacted with liquid fluoride and worked up analogously to Example A, giving 18 g of the compound (2) in a purity of 96% (GC). (Yield: 92% of theory).

Sources & evidence

ORD record
ord-9da32c849b2c46aa9f9888538ed61e19
Source dataset
uspto-grants-1994_07
Patent number
US05329049

Reaction notes

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