HuagongsheHuagongshe Chemistry Print Report · For research reference only
P-Xylene → 2,3-Dihydro-3,3,4,7-tetramethyl-1H-inden-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | P-Xylene | HCID 7809 | — |
| Reactant | Ethyl 3,3-dimethylacrylate | HCID 12516 | — |
| Reactant | Fluoride Ion | HCID 28179 | — |
| Product | 2,3-Dihydro-3,3,4,7-tetramethyl-1H-inden-1-one | HCID 19016928 | 95.6% |
Reaction Steps
10.6 g (100 mmol) of p-xylene (99% purity) and 14.4 g (112 mmol) of ethyl 3,3-dimethylacrylate were reacted with liquid fluoride and worked up analogously to Example A, giving 18 g of the compound (2) in a purity of 96% (GC). (Yield: 92% of theory).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05329049 |
| Source dataset | uspto-grants-1994_07 |
| ORD ID | ord-9da32c849b2c46aa9f9888538ed61e19 |
| Source note | uspto-grants-1994_07 |