Hydroxyamine hydrochloride → HCID 86748007, compound

HRID 1729378Notes

Reaction equation

[CH3:1][CH:2]1[O:6][C:5]([C:8]2[CH:9]=[C:10]([S:14][C:15]3[CH:20]=[CH:19][C:18]([C:21](=O)[CH3:22])=[CH:17][CH:16]=3)[CH:11]=[CH:12][CH:13]=2)([CH3:7])[CH2:4][O:3]1.Cl.[NH2:25][OH:26]>>[CH3:1][CH:2]1[O:6][C:5]([C:8]2[CH:9]=[C:10]([S:14][C:15]3[CH:20]=[CH:19][C:18]([C:21](=[N:25][OH:26])[CH3:22])=[CH:17][CH:16]=3)[CH:11]=[CH:12][CH:13]=2)([CH3:7])[CH2:4][O:3]1

Participants

Reactant 2

HCID 443297Hydroxyamine hydrochloride

HCID 18996126HCID 18996126, compound

Product 1

HCID 86748007HCID 86748007, compoundYield 82%

Procedure

Using an analogous procedure to that described in Example 68, 4'-[3-(2,4-dimethyl-1,3-dioxolan-4-yl)phenylthio]acetophenone was reacted with hydroxylamine hydrochloride to give 4'-[3-(2,4-dimethyl-1,3-dioxolan-4-yl)phenylthio]acetophenone oxime in 82% yield as a gum.

Sources & evidence

ORD record: ord-98f94dedcc6f4a97854af42435b5e176
Source dataset: uspto-grants-1994_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05332757

Reaction notes

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