HuagongsheHuagongshe Chemistry Print Report · For research reference only
5-Bromo-4-methylpyridine-2,3-diamine → 6-Bromo-2-butyl-7-methylimidazo[4,5-b]pyridine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5-Bromo-4-methylpyridine-2,3-diamine | HCID 10125141 | — |
| Reactant | 2-butyl-1H-imidazo[4,5-b]pyridine | HCID 12467710 | — |
| Product | 6-Bromo-2-butyl-7-methylimidazo[4,5-b]pyridine | HCID 21464181 | — |
Reaction Steps
The title compound was prepared according to the procedure described for the preparation of 2-butylimidazo[4,5-b]pyridine starting with 5-bromo-2,3-diamino-4-picoline. Yield: 2.54 g (95%) of an amorphous solid: 1H NMR (250 MHz, CDCl3) δ 8.45 (s 1H), 3.05 (t, 2H, J=7 Hz), 2.73 (s, 3H), 2.02-1.87 (m, 2H), 1.61-1.45 (m, 2H), 1.02 (t, 3H, J=7 Hz).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05332744 |
| Source dataset | uspto-grants-1994_07 |
| ORD ID | ord-4b7e69716dc0487a92122d9fef7be079 |
| Source note | uspto-grants-1994_07 |