HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Dibromoethane → Hydrogen Bromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,2-Dibromoethane | HCID 7839 | — |
| Reactant | 1-Phenyl-1H-benzoimidazol-2-ylamine | HCID 2773197 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Hydrogen Bromide | HCID 260 | 54.1% |
| Product | HCID 13077475 | HCID 13077475 | — |
Reaction Steps
A solution of 2-amino-3-phenylbenzimidazole (4.18 g., 0.02 mole) and 1,2-dibromoethane (7.52 g., 0.04 mole) in toluene (40 ml.) was heated under reflux for 24 hours. After removal of the solvent the residual oil was crystallised from ethanol/ether. The product (0.950 g.) was recrystallised from ethanol/ether to give the title compound as its hydrobromide (0.875 g., m.p. 225°-228° C).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03989709 |
| Source dataset | uspto-grants-1976_11 |
| ORD ID | ord-98646f4f10034ccdaf0d991b5cc35b2e |
| Source note | uspto-grants-1976_11 |