Methanethiol → 2-Pyrazinyl-ethyl methyl sulfide

HRID 1729736Notes

Reaction equation

HRID 1729736 reaction equation
[CH:1]([C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1)=[CH2:2].[CH3:9][SH:10].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>>[CH3:9][S:10][CH2:2][CH2:1][C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1

Participants

4

Reactant 3

HCID 878MethanethiolHCID 7187Benzoyl PeroxideHCID 77840Vinylpyrazine

Product 1

HCID 226304002-Pyrazinyl-ethyl methyl sulfide

Procedure

h. 2-Pyrazinyl-ethyl methyl sulfide was prepared by reacting vinylpyrazine [c.f. J.Org.Chem. 27, 1363 (1962)] with methylmercaptan by the action of ultra violet light and in the presence of benzoyl peroxide by the method described in Acta Chem. Scand. 8, 295 (1954). The product was identified by mass spectrometry. It has a b.p. of 57°-69° C. at 0.05 mm. Hg.

Sources & evidence

ORD record
ord-36ad13a4c9b14ca4b07e56790abfbb20
Source dataset
uspto-grants-1976_11
Patent number
US03989713

Reaction notes

Loading…