4-Chlorobenzoyl chloride → HCID 54359873, compound

HRID 1729760Notes

Reaction equation

HRID 1729760 reaction equation
[CH2:1]([O:3][NH:4][C:5](=[C:8]1[C:13](=[O:14])[CH2:12][C:11]([CH3:16])([CH3:15])[CH2:10][C:9]1=[O:17])[CH2:6][CH3:7])[CH3:2].[Cl:18][C:19]1[CH:27]=[CH:26][C:22]([C:23](Cl)=[O:24])=[CH:21][CH:20]=1>C(Cl)(Cl)Cl>[Cl:18][C:19]1[CH:27]=[CH:26][C:22]([C:23]([O:17][C:9]2[CH2:10][C:11]([CH3:15])([CH3:16])[CH2:12][C:13](=[O:14])[C:8]=2[C:5](=[N:4][O:3][CH2:1][CH3:2])[CH2:6][CH3:7])=[O:24])=[CH:21][CH:20]=1

Participants

4

Reactant 2

HCID 85014-Chlorobenzoyl chlorideHCID 178474720HCID 178474720, compound

Product 1

HCID 54359873HCID 54359873, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

The same reaction procedures as Example 1 were carried out by using 2.4 g of 2-[1-(N-ethoxyamino)propylidene]-5,5-dimethylcyclohexane-1,3-dione and 1.75 g of 4-chlorobenzoylchloride, and chloroform was distilled off under reduced pressure and thereby the desired product as a white crystal was obtained after recrystallization the residual material from n-hexane.

Workup

  1. customThe same reaction procedures as Example 1
  2. distillationwas distilled off under reduced pressure

Sources & evidence

ORD record
ord-4e48ab3a877c4b018efac6395b91e60b
Source dataset
uspto-grants-1976_11
Patent number
US03989737

Reaction notes

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