HuagongsheHuagongshe Chemistry Print Report · For research reference only
Pyridine → tert-Butyl 3-[(chlorocarbonyl)oxy]propaneperoxoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Pyridine | HCID 1049 | — |
| Reactant | Phosgene | HCID 6371 | — |
| Reactant | Pentane | HCID 8003 | — |
| Reactant | tert-Butyl 3-hydroxypropaneperoxoate | HCID 20371803 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | tert-Butyl 3-[(chlorocarbonyl)oxy]propaneperoxoate | HCID 20559661 | — |
Reaction Steps
To 75 ml. of pentane at -10° to +5° C was added 39.6g. of phosgene. To this mixture was added a mixture of t-butyl-3-hydroxyperoxypropionate (38g. 0.2 moles of 85% pure products) and pyridine (15.8g. 0.2 moles) in diethyl ether over a period of one hour.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03991109 |
| Source dataset | uspto-grants-1976_11 |
| ORD ID | ord-c79b6488d4a1408e93f11e8622c3c1ca |
| Source note | uspto-grants-1976_11 |