Pyridine → tert-Butyl 3-[(chlorocarbonyl)oxy]propaneperoxoate

HRID 1730106Notes

Reaction equation

HRID 1730106 reaction equation
CCCCC.[C:6](Cl)([Cl:8])=[O:7].[C:10]([O:14][O:15][C:16](=[O:20])[CH2:17][CH2:18][OH:19])([CH3:13])([CH3:12])[CH3:11].N1C=CC=CC=1>C(OCC)C>[Cl:8][C:6]([O:19][CH2:18][CH2:17][C:16]([O:15][O:14][C:10]([CH3:13])([CH3:11])[CH3:12])=[O:20])=[O:7]

Participants

6

Reactant 4

HCID 1049PyridineHCID 6371PhosgeneHCID 8003PentaneHCID 20371803tert-Butyl 3-hydroxypropaneperoxoate

Product 1

HCID 20559661tert-Butyl 3-[(chlorocarbonyl)oxy]propaneperoxoate

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To 75 ml. of pentane at -10° to +5° C was added 39.6g. of phosgene. To this mixture was added a mixture of t-butyl-3-hydroxyperoxypropionate (38g. 0.2 moles of 85% pure products) and pyridine (15.8g. 0.2 moles) in diethyl ether over a period of one hour.

Workup

  1. additionTo this mixture was added

Sources & evidence

ORD record
ord-c79b6488d4a1408e93f11e8622c3c1ca
Source dataset
uspto-grants-1976_11
Patent number
US03991109

Reaction notes

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