HCID 21497540, compound → HCID 21497570, compound

HRID 1730392Notes

Reaction equation

HRID 1730392 reaction equation
[C:1]1(=[O:19])[N:5]([CH2:6][C:7](=[O:13])[CH:8]([N:10]=[N+]=[N-])[CH3:9])[C:4](=[O:14])[C:3]2=[CH:15][CH:16]=[CH:17][CH:18]=[C:2]12>C(OCC)(=O)C.[Pd]>[C:4]1(=[O:14])[N:5]([CH2:6][C:7](=[O:13])[CH:8]([NH2:10])[CH3:9])[C:1](=[O:19])[C:2]2=[CH:18][CH:17]=[CH:16][CH:15]=[C:3]12

Participants

4

Reactant 1

HCID 21497540HCID 21497540, compound

Product 1

HCID 21497570HCID 21497570, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8857Ethyl AcetateSolvent

Procedure

In the manner given in example 4, 1-phthalimido-3-azido-2-butanone, ethylene ketal in ethyl acetate is reduced with molecular hydrogen and palladium on charcoal to give 1-phthalimido-3-amino-2-butanone, ethylene ketal.

Sources & evidence

ORD record
ord-a5bbcf400b8c446c8661c17b02723103
Source dataset
uspto-grants-1976_11
Patent number
US03992408

Reaction notes

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