Picolyl chloride → 2-({2-[2-(5-Nitrofuran-2-yl)ethenyl]-1H-imidazol-1-yl}methyl)pyridine

HRID 1730623Notes

Reaction equation

HRID 1730623 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[CH2:7]Cl.[N+:9]([C:12]1[O:16][C:15]([CH:17]=[CH:18][C:19]2[NH:20][CH:21]=[CH:22][N:23]=2)=[CH:14][CH:13]=1)([O-:11])=[O:10]>>[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[CH2:7][N:23]1[CH:22]=[CH:21][N:20]=[C:19]1[CH:18]=[CH:17][C:15]1[O:16][C:12]([N+:9]([O-:11])=[O:10])=[CH:13][CH:14]=1

Participants

3

Reactant 2

HCID 23393Picolyl chlorideHCID 286751HCID 286751, compound

Product 1

HCID 542759612-({2-[2-(5-Nitrofuran-2-yl)ethenyl]-1H-imidazol-1-yl}methyl)pyridine

Procedure

Using the same general procedure of Example 1, the captioned compound was prepared using 2-picolyl chloride and 2-[2-(5-nitro-2-furyl)vinyl]imidazole. The resulting yellow product was recrystallized from benzene-petroleum ether and melted at 141°-142°.

Workup

  1. customthe captioned compound was prepared
  2. customThe resulting yellow product was recrystallized from benzene-petroleum ether and melted at 141°-142°

Sources & evidence

ORD record
ord-95bf728e56d24defb8d8211077171fc3
Source dataset
uspto-grants-1976_11
Patent number
US03993643

Reaction notes

Loading…