HuagongsheHuagongshe Chemistry Print Report · For research reference only
Malonic Acid → HCID 20535692, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Malonic Acid | HCID 867 | — |
| Reactant | 2-Thiophenecarboxaldehyde | HCID 7364 | — |
| Reactant | Piperidine | HCID 8082 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Product | HCID 20535692 | HCID 20535692 | — |
Reaction Steps
2-thienyl acrylic acid was prepared by reaction of 2-thiophene carboxaldehyde with malonic acid. A solution of 2-thiophene carboxaldehyde (25.7 g.), malonic acid (41.6 g.), pyridine (100 ml.), and piperidine (2 ml.) was refluxed for 31/2 hours. 2-thienyl acrylic acid was recovered from the reaction mixture in a manner parallel to that described in Example 41.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03993684 |
| Source dataset | uspto-grants-1976_11 |
| ORD ID | ord-c12c374d007e410e810daad40783549c |
| Source note | uspto-grants-1976_11 |