1-Bromo-2-naphthol → 1-Bromo-2-methoxynaphthalene

HRID 1731063Notes

Reaction equation

HRID 1731063 reaction equation
[Br:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][C:3]=1[OH:12].[I:13][C:14]1[C:23]2[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:17]=[CH:16][C:15]=1[OH:24]>>[Br:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][C:3]=1[O:12][CH3:14].[I:13][C:14]1[C:23]2[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:17]=[CH:16][C:15]=1[O:24][CH3:2]

Participants

4

Reactant 2

HCID 113161-Bromo-2-naphtholHCID 162502-Naphthol, 1-iodo-

Product 2

HCID 728601-Bromo-2-methoxynaphthaleneHCID 2694931-iodo-2-methoxynaphthalene

Procedure

Repeating this procedure with 1-bromo-2-hydroxynaphthalene or 1-iodo-2-hydroxynaphthalene yields 1-bromo-2-methoxynaphthalene or 1-iodo-2-methoxynaphthalene, respectively.

Sources & evidence

ORD record
ord-26af7993ddd14db9beadc03500ebcd1c
Source dataset
uspto-grants-1976_11
Patent number
US03994968

Reaction notes

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