O-Allylhydroxylamine → HCID 178460155, compound

HRID 1731720Notes

Reaction equation

HRID 1731720 reaction equation
[C:1]([CH:6]1[C:11](=[O:12])[CH2:10][CH:9]([CH2:13][CH2:14][N:15]2[C:19]([CH3:20])=[CH:18][C:17]([CH3:21])=[N:16]2)[CH2:8][C:7]1=[O:22])(=O)[CH2:2][CH2:3][CH3:4].[CH2:23]([O:26][NH2:27])[CH:24]=[CH2:25]>C(O)C>[CH2:23]([O:26][NH:27][C:1](=[C:6]1[C:11](=[O:12])[CH2:10][CH:9]([CH2:13][CH2:14][N:15]2[C:19]([CH3:20])=[CH:18][C:17]([CH3:21])=[N:16]2)[CH2:8][C:7]1=[O:22])[CH2:2][CH2:3][CH3:4])[CH:24]=[CH2:25]

Participants

4

Reactant 2

HCID 420841O-AllylhydroxylamineHCID 20226955HCID 20226955, compound

Product 1

HCID 178460155HCID 178460155, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

10 parts by weight of 2-butyryl-5-[2-(3,5-dimethylpyrazol-1-yl)-ethyl]-cyclohexane-1,3-dione and 2.5 parts by weight of allyloxyamine in 100 parts by volume of ethanol were stirred for 12 hours at room temperature. The mixture was worked up by a method similar to that described in Example 1. 8.8 parts by weight of 2-(1-allyloxyaminobutylidene)-5-[2-(3,5-dimethylpyrazol-1-yl)-ethyl]-cyclohexane-1,3-dione of nD28 =1.5329 were obtained (Compound No. 2).

Sources & evidence

ORD record
ord-fa47602b52a544c79abfd31545ed9b25
Source dataset
uspto-grants-1986_11
Patent number
US04623381

Reaction notes

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