Cumene → HCID 86737389, compound

HRID 1732817Notes

Reaction equation

HRID 1732817 reaction equation
[O-:1][OH:2].[C:3]1([CH:9]([CH3:11])[CH3:10])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH3:12][CH:13]([CH3:22])[C:14]1[CH:19]=[CH:18][CH:17]=[C:16]([CH2:20]O)[CH:15]=1.C1(C(C)C)C=CC=CC=1>>[C:9]([O:1][O:2][C:15]1[C:16]([CH3:20])=[CH:17][CH:18]=[CH:19][C:14]=1[CH:13]([CH3:22])[CH3:12])([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1)([CH3:11])[CH3:10]

Participants

4

Reactant 3

HCID 7406CumeneHCID 20301459[3-(Propan-2-yl)phenyl]methanolHCID 53627471Cumen hydroperoxide

Product 1

HCID 86737389HCID 86737389, compoundYield 90%

Procedure

To a mixture of 76 g (0.5 mole) of cumene hydroperoxide, 75 g (0.5 mole) of α,α-dimethyl-m-tolylcarbinol and 15 g of cumene was added 2 g of synthetic silica-alumina, and reaction was carried out at 60° C. for 3 hours while blowing nitrogen, to obtain cumyl-m-cymylperoxide in a yield of 90%.

Workup

  1. additionwas added
  2. custom2 g of synthetic silica-alumina, and reaction

Sources & evidence

ORD record
ord-f13d77a5f6da48f5b9d60db9c6cf7fbb
Source dataset
uspto-grants-1980_12
Patent number
US04239644

Reaction notes

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