Benzhydrol → Benzophenone

HRID 1732856Notes

Reaction equation

HRID 1732856 reaction equation
[C:1]1([CH:7]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[O-]Cl.[Na+].CCCCCCCC(C([NH3+])(C(CCCCCCC)=O)C(CCCCCCC)=O)=O.[Cl-]>CCOC(C)=O>[C:7]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)(=[O:8])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 3

HCID 7037BenzhydrolHCID 23665760Sodium HypochloriteHCID 77620884Tricaprylylmethyl ammonium chloride

Product 1

HCID 3102Benzophenone

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

5 g (27.17 moles) of diphenyl-methanol dissolved in 55 ml of AcOEt (RPE Carlo Erba) were added to 177 ml of a commercial solution (RPE Carlo Erba) of NaOCl (about 271.7 moles) containing 1.65 g (about 4.1 moles) of Aliquat-336.

Sources & evidence

ORD record
ord-114f8704030f41eea42e8b9036b3ad79
Source dataset
uspto-grants-1980_12
Patent number
US04239702

Reaction notes

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