Water → HCID 70597034, compound

HRID 1733038Notes

Reaction equation

HRID 1733038 reaction equation
[CH:1]([N:4]=[CH:5][CH:6]=[C:7]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)[CH3:8])([CH3:3])[CH3:2].[H-].[H-].[H-].[H-].[Li+].[Al+3].O>CCOCC>[CH:1]([NH:4][CH2:5][CH:6]=[C:7]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)[CH3:8])([CH3:3])[CH3:2]

Participants

5

Reactant 3

HCID 962WaterHCID 21226445Aluminium lithium hydrideHCID 70596907HCID 70596907, compound

Product 1

HCID 70597034HCID 70597034, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent2×

Procedure

A solution of 2.63 g of 1-isopropylimino-3-p-biphenylyl-2-butene (obtainable from 3-p-biphenylyl-2-butenal and isopropylamine) in 20 ml of absolute ether is added dropwise to a solution of 0.6 g of LiAlH4 in 20 ml of absolute ether. The mixture is then boiled for 5 hours, water is added carefully and the mixture is worked up in the customary manner to give 1-isopropylamino-3-p-biphenylyl-2-butene.

Sources & evidence

ORD record
ord-d43e9b639c4140a9827c21e5c27a6327
Source dataset
uspto-grants-1980_12
Patent number
US04239759

Reaction notes

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