Peracetic Acid → HCID 12637736, compound

HRID 1733138Notes

Reaction equation

HRID 1733138 reaction equation
[N+:1]([C:4]1[C:12]2[S:11][C:10](=[S:13])[S:9][C:8]=2[CH:7]=[C:6]([C:14]([F:17])([F:16])[F:15])[CH:5]=1)([O-:3])=[O:2].C(OO)(=[O:20])C>C(Cl)(Cl)Cl>[N+:1]([C:4]1[C:12]2[S:11][C:10](=[S:13]=[O:20])[S:9][C:8]=2[CH:7]=[C:6]([C:14]([F:17])([F:16])[F:15])[CH:5]=1)([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 6585Peracetic AcidHCID 126377344-Nitro-6-(trifluoromethyl)-1,3-benzodithiole-2-thione

Product 1

HCID 12637736HCID 12637736, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

To a stirred solution of 7.35 g., (24.7 mmoles) of 4-nitro-6-trifluoromethyl-1,3-benzodithiole-2-thione in 150 ml. of chloroform was added dropwise a solution of 5.17 g., (24.7 mmoles) of 40% peracetic acid in 50 ml. of chloroform over a period of 20 minutes, the temperature being maintained at 8°-12° C.

Workup

  1. temperaturethe temperature being maintained at 8°-12° C.

Sources & evidence

ORD record
ord-1c86db5ac56747db9df172dd3dc874dc
Source dataset
uspto-grants-1980_12
Patent number
US04240821

Reaction notes

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