HRID1733824

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=C(C=P(c1ccccc1)(c1ccccc1)c1ccccc1)CCl

HCID287004

2-Propanone, 1-chloro-3-(triphenylphosphoranylidene)-

C21H18ClOP

HCID5360545

Sodium

结构：CC(C)OCC(=O)C=P(c1ccccc1)(c1ccccc1)c1ccccc1

HCID15016599

未命名化合物

PRODUCTS

生成物

结构：CC(C)OCCC(=O)C=P(c1ccccc1)(c1ccccc1)c1ccccc1

HCID15016572

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID11428

3-Pentanol

C5H12O

PROCEDURE

实验过程

A solution of 3.04 g of sodium in 100 ml of 3-pentanol is reacted with 25.0 g of chloromethylcarbonylmethylenetriphenyl phosphorane analogously to the production of isopropoxymethylcarbonylmethylenetriphenyl phosphorane. The title compound is obtained as crystallized oil with a melting point of 66°-70° C.