HRID1734712

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID1140

Toluene

C7H8

HCID6278

1,1,1-Trichloroethane

C2H3Cl3

结构：CCOP(=O)(OCC)c1nc(NC(C)C)nc(NC(C)C)n1

HCID19438222

未命名化合物

PRODUCTS

生成物

HCID4937

2,4-Bis(isopropylamino)-6-chloro-1,3,5-triazine

C9H16ClN5

收率 12%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID31275

1,4-Dioxane

C4H8O2

PROCEDURE

实验过程

Similar reactions, in which 1,1,1-trichloroethane (reflux 75° C.) and 1,4-dioxan (reflux 105° C.) were used as solvents instead of toluene, both gave diethyl 2,4-bis(isopropylamino)-1,3,5-triazine-6-phosphonate in 81% yield, together with 2-chloro-4,6-bis(isopropylamino)-1,3,5-triazine (yield 12-17%).