Triethylamine → HCID 19438408, compound

HRID 1734767Notes

Reaction equation

HRID 1734767 reaction equation
Cl[P:2]1[N:5]([C:6]([CH3:9])([CH3:8])[CH3:7])[P:4](Cl)[N:3]1[C:11]([CH3:14])([CH3:13])[CH3:12].[CH2:15]([NH:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH3:51])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32].C([N:54]([CH2:57][CH3:58])[CH2:55][CH3:56])C>C1(C)C=CC=CC=1>[CH2:34]([N:33]([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32])[P:2]1[N:5]([C:6]([CH3:9])([CH3:8])[CH3:7])[P:4]([N:54]([CH2:55][CH2:56][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH3:15])[CH2:57][CH2:58][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])[N:3]1[C:11]([CH3:14])([CH3:13])[CH3:12])[CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH3:51]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 66989DioctadecylamineHCID 125327951,3-Di-tert-butyl-2,4-dichloro-1,3,2,4-diazadiphosphetidine

Product 1

HCID 19438408HCID 19438408, compoundYield 89.2%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

The procedure of Example 1 is repeated using 5 g (18 mmol) of 2,4-dichloro-1,3-di-tert-butyl-1,3,2,4-diazadiphosphetidine, 18.8 g (36 mmol) of dioctadecylamine, 5 mL (36 mmol) of triethylamine and 200 mL of toluene to give 20 g of a wet solid. Recrystallization of the crude solid with a mixture of 45 mL of acetonitrile and 5 mL of toluene gives 10 g (50% yield) of the title compounds as a white solid melting at 48°-55° C.

Sources & evidence

ORD record
ord-ab40866e8bcc4cabb77f106a1091df03
Source dataset
uspto-grants-1996_07
Patent number
US05534646

Reaction notes

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