Triethylamine → HCID 18468907, compound

HRID 1739526Notes

Reaction equation

HRID 1739526 reaction equation
Cl[Si:2]([CH3:18])([CH3:17])[CH:3]1[C:14]2[C:6](=[CH:7][C:8]3[CH2:9][CH2:10][CH2:11][C:12]=3[CH:13]=2)[C:5]([CH3:15])=[C:4]1[CH3:16].CC[N:21]([CH2:24][CH3:25])CC>CCCCCC>[CH:24]1([NH:21][Si:2]([CH3:18])([CH3:17])[CH:3]2[C:14]3[C:6](=[CH:7][C:8]4[CH2:9][CH2:10][CH2:11][C:12]=4[CH:13]=3)[C:5]([CH3:15])=[C:4]2[CH3:16])[CH2:25][CH2:5][CH2:4][CH2:3][CH2:14]1

Participants

4

Reactant 2

HCID 8471TriethylamineHCID 18468872HCID 18468872, compound

Product 1

HCID 18468907HCID 18468907, compoundYield 181%

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Chlorodimethyl(1,5,6,7-tetrahydro-2,3-dimethyl-s-indacen-1-yl)silane (5.00 g, 0.01806 moles) was stirred in hexane (80 mL) as NEt3 (3.29 g, 0.03251 moles) and t-cyclohexylamine (1.81 g, 0.01824 moles) were added. This mixture was allowed to stir 16 hours. After the reaction period the mixture was filtered and the volatiles removed resulting in the isolation of the desired product as a yellow oil (5.55 g, 90.9 percent).

Workup

  1. additionwere added
  2. customAfter the reaction period the mixture
  3. filtrationwas filtered
  4. customthe volatiles removed

Sources & evidence

ORD record
ord-230593d152ef400f993aca92c16a7111
Source dataset
uspto-grants-1999_10
Patent number
US05965756

Reaction notes

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