Hydrogen Peroxide → HCID 53778012, compound

HRID 1740281Notes

Reaction equation

HRID 1740281 reaction equation
[CH2:1]([O:3][C:4](=[O:26])[C:5]([Cl:25])([Cl:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][S:16][C:17]1[CH:22]=[CH:21][C:20]([Cl:23])=[CH:19][CH:18]=1)[CH3:2].[OH:27]O>C(O)(=O)C>[CH2:1]([O:3][C:4](=[O:26])[C:5]([Cl:25])([Cl:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][S:16]([C:17]1[CH:18]=[CH:19][C:20]([Cl:23])=[CH:21][CH:22]=1)=[O:27])[CH3:2]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 537675782,2-Dichloro-12-(4-chlorophenylsulfenyl)-dodecanoic acid ethyl ester

Product 1

HCID 53778012HCID 53778012, compoundYield 99%

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

2.0 g (4.55 mmol) 104 and 6 ml 30% hydrogen peroxide in 20 ml glacial acetic acid were oxidized to form 2.08 g (99%) 106 as a colourless oil analogously to 78 (example 26).

Sources & evidence

ORD record
ord-8ae303a356da4dd49a661a95efcd2c8e
Source dataset
uspto-grants-1999_10
Patent number
US05968982

Reaction notes

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