Chloroacetaldehyde → HCID 69932725, compound

HRID 1740326Notes

Reaction equation

HRID 1740326 reaction equation
[C:1]1([OH:9])[C:2](C)=[CH:3][CH:4]=[CH:5][C:6]=1[CH3:7].[C:10]([C:14]1[CH:19]=[CH:18][C:17](C)=[CH:16][C:15]=1[OH:21])(C)(C)C.ClCC=O>>[C:1]1([OH:9])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1.[C:15]1([OH:21])[CH:16]=[CH:17][CH:18]=[CH:19][CH:14]=1.[C:14]1([CH:10]=[CH:7][C:6]2[CH:1]=[CH:2][CH:3]=[CH:4][CH:5]=2)[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Participants

4

Reactant 3

HCID 33ChloroacetaldehydeHCID 69376-tert-Butyl-m-cresolHCID 113352,6-Dimethylphenol2×

Product 1

HCID 69932725HCID 69932725, compoundYield 705.6%

Procedure

An amount of 195.5 g (0.16 mol) 2,6-xylenol (hereinafter referred to "26XY"), 65.7 g (0.4 mol) of 2-t-butyl-5-methylphenol and 174.4 g (1.0 mol) of an aqueous 45% chloroacetoaldehyde solution were charged in a flask and stilbene bisphenol (yellow crystal 208 g) was obtained according to the method described in R. H. Siebe, Liebigs, Ann. Chem., 730, 31 (1969).

Workup

  1. additionwere charged in a flask

Sources & evidence

ORD record
ord-0725afe98c014446857d6cc129627bf5
Source dataset
uspto-grants-1999_10
Patent number
US05969060

Reaction notes

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