Perchloric Acid → 183583-04-2

HRID 1741276Notes

Reaction equation

HRID 1741276 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]([CH3:12])=[CH:9][O:10]C.Cl(O)(=O)(=O)=O>CCOCC>[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH:8]([CH3:12])[CH:9]=[O:10]

Participants

4

Reactant 2

HCID 24247Perchloric AcidHCID 54493149HCID 54493149, compound

Product 1

HCID 21835204183583-04-2

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent2×

Procedure

To a solution of 2-(2-chlorophenyl)-1-methoxypropene (712 mg, 3.9 mmol) in ether (8 ml) at 0° C. was added perchloric acid (70%, 3 ml). After stirring for 1 h the solution was diluted with ether (8 ml) and washed with water (2×20 ml). The organic phase was separated, dried (Na2SO4) and evaporated. The crude 2-(2-chlorophenyl)propanal was isolated as a colourless oil and used without further purification.

Workup

  1. washwashed with water (2×20 ml)
  2. customThe organic phase was separated
  3. dry with materialdried (Na2SO4)
  4. customevaporated

Sources & evidence

ORD record
ord-5010c68538e043bc9e36acd23bfe54e7
Source dataset
uspto-grants-1999_10
Patent number
US05973156

Reaction notes

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