Potassium Carbonate → HCID 15217301, compound

HRID 1741563Notes

Reaction equation

HRID 1741563 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]([C:16]2[C:29]3[C:30]4=[C:31]5[C:26](=[CH:27][CH:28]=3)[CH:25]=[CH:24][CH:23]=[C:22]5[CH:21]=[CH:20][C:19]4=[CH:18][CH:17]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[C:11]([NH2:15])[CH:10]=2)=[CH:4][CH:3]=1.I[C:33]1[CH:38]=[CH:37][C:36]([CH3:39])=[CH:35][CH:34]=1.C(=O)([O-])[O-].[K+].[K+]>[Cu]>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]([C:16]2[C:29]3[C:30]4=[C:31]5[C:26](=[CH:27][CH:28]=3)[CH:25]=[CH:24][CH:23]=[C:22]5[CH:21]=[CH:20][C:19]4=[CH:18][CH:17]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[C:11]([N:15]([C:5]3[CH:6]=[CH:7][C:2]([CH3:1])=[CH:3][CH:4]=3)[C:33]3[CH:38]=[CH:37][C:36]([CH3:39])=[CH:35][CH:34]=3)[CH:10]=2)=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 122074-IodotolueneHCID 15217300HCID 15217300, compound

Product 1

HCID 15217301HCID 15217301, compound

Reagents, catalysts & solvents 1

HCID 23978CopperCatalyst

Procedure

A mixture of 2.79 g (7.00 mmol) of N-(4-methylphenyl)-N-(3-aminophenyl)-1-pyrenylamine synthesized in Synthesis Example 2, 15.3 g (70.0 mmol) of 4-iodotoluene, 3.87 g of potassium carbonate, and 0.44 g of copper powder was subjected to azeotropic dehydration in a stream of nitrogen, using an ester tube, with stirring, at 209° to 212° C. for 10 hours.

Sources & evidence

ORD record
ord-488c501f6fcd408ba1c6ac0e6580c7eb
Source dataset
uspto-grants-1994_08
Patent number
US05334470

Reaction notes

Loading…