Pyridine → HCID 19010253, compound

HRID 1741564Notes

Reaction equation

HRID 1741564 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:7][CH2:8][C:9]1[CH:16]=[CH:15][C:12]([CH:13]=[O:14])=[CH:11][CH:10]=1>CO>[Br-:7].[CH:13]([C:12]1[CH:15]=[CH:16][C:9]([CH2:8][N+:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)=[CH:10][CH:11]=1)=[O:14]

Participants

4

Reactant 2

HCID 1049PyridineHCID 112064214-(Bromomethyl)benzaldehyde

Product 1

HCID 19010253HCID 19010253, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

Reactants (1) and (2) were added together in MeOH to ultimately result in about 20-26 wt-% of (3) in MeOH in a flask as illustrated above in Table I. All reactant mixtures A through D were divided by MeOH (abs), to reduce viscosity. The mixtures were allowed to stir overnight at room temperature. It was observed that Trials C and D had formed a white rubber polymer. Addition of methanol and stirring for 1 hour did not dissolve the polymeric material.

Sources & evidence

ORD record
ord-e6cacae9ddca416a82c25898a93d0832
Source dataset
uspto-grants-1994_08
Patent number
US05334485

Reaction notes

Loading…