Phenol → HCID 19006645, compound

HRID 1742552Notes

Reaction equation

[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][C:9]([S:12](Cl)(=[O:14])=[O:13])=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[C:16]1([S:22](Cl)(=[O:24])=[O:23])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[C:26]1([OH:33])[CH:31]=[CH:30][CH:29]=[C:28]([OH:32])[CH:27]=1.[C:34]1([OH:40])C=C[CH:37]=[CH:36][CH:35]=1>>[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][C:9]([S:12]([O:32][C:28]2[CH:29]=[CH:30][CH:31]=[C:26]([O:33][S:22]([C:16]3[CH:21]=[CH:20][C:19]([O:40][CH2:34][CH2:35][CH2:36][CH3:37])=[CH:18][CH:17]=3)(=[O:24])=[O:23])[CH:27]=2)(=[O:14])=[O:13])=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4]

Participants

Reactant 4

HCID 996Phenol

HCID 5054Resorcinol

HCID 7369Benzenesulfonyl chloride

HCID 5179904-Butoxybenzenesulfonyl Chloride

Product 1

HCID 19006645HCID 19006645, compound

Procedure

The procedure of Example 1 is substantially repeated except two equivalents of 4-n-butoxybenzenesulfonyl chloride is substituted for the benzenesulfonyl chloride and 1,3-benzenediol is substituted for the phenol. The resulting disulfonate is a thick oil having PDSC onset/extrapolated temperatures of 286/292.

Sources & evidence

ORD record: ord-dc2457f7b95943cf9e5c2e3d0e43430a
Source dataset: uspto-grants-1994_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05340489

Reaction notes

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