Diisopropylaniline → HCID 10094999, compound

HRID 1742659Notes

Reaction equation

[N+:1]([C:4]1[CH:21]=[CH:20][C:7]2[O:8][CH2:9][C:10]3[CH:19]=[CH:18][CH:17]=[CH:16][C:11]=3[CH:12]([C:13](O)=[O:14])[C:6]=2[CH:5]=1)([O-:3])=[O:2].[CH:22]([C:25]1[CH:31]=[CH:30][CH:29]=[C:28]([CH:32]([CH3:34])[CH3:33])[C:26]=1[NH2:27])([CH3:24])[CH3:23]>>[CH:32]([C:28]1[CH:29]=[CH:30][CH:31]=[C:25]([CH:22]([CH3:24])[CH3:23])[C:26]=1[NH:27][C:13]([CH:12]1[C:11]2[CH:16]=[CH:17][CH:18]=[CH:19][C:10]=2[CH2:9][O:8][C:7]2[CH:20]=[CH:21][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][C:6]1=2)=[O:14])([CH3:34])[CH3:33]

Participants

Reactant 2

HCID 32484Diisopropylaniline

HCID 10107980HCID 10107980, compound

Product 1

HCID 10094999HCID 10094999, compoundYield 45.3%

Procedure

The similar procedures as in Example 1 were repeated except using 1.18 g of 6,11-dihydro-2-nitrodibenz[b,e]oxepin-11-carboxylic acid obtained in Example 62 (Compound AA) in place of Compound A and 0.73 g of 2,6-diisopropylaniline in place of aniline to obtain 0.83 g of Compound 46.

Sources & evidence

ORD record: ord-e4f4bf3e340349ad9566dcdbd74c23a0
Source dataset: uspto-grants-1994_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05340807

Reaction notes

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