Diisopropylaniline → HCID 10432688, compound

HRID 1742660Notes

Reaction equation

[CH3:1][C:2]1[C:19]([CH3:20])=[CH:18][C:5]2[O:6][CH2:7][C:8]3[CH:17]=[CH:16][CH:15]=[CH:14][C:9]=3[CH:10]([C:11]([OH:13])=O)[C:4]=2[CH:3]=1.[CH:21]([C:24]1[CH:30]=[CH:29][CH:28]=[C:27]([CH:31]([CH3:33])[CH3:32])[C:25]=1[NH2:26])([CH3:23])[CH3:22]>>[CH:31]([C:27]1[CH:28]=[CH:29][CH:30]=[C:24]([CH:21]([CH3:23])[CH3:22])[C:25]=1[NH:26][C:11]([CH:10]1[C:9]2[CH:14]=[CH:15][CH:16]=[CH:17][C:8]=2[CH2:7][O:6][C:5]2[CH:18]=[C:19]([CH3:20])[C:2]([CH3:1])=[CH:3][C:4]1=2)=[O:13])([CH3:33])[CH3:32]

Participants

Reactant 2

HCID 32484Diisopropylaniline

HCID 10015858HCID 10015858, compound

Product 1

HCID 10432688HCID 10432688, compoundYield 93.4%

Procedure

The similar procedures as in Example 1 were repeated except using 0.84 g of 6,11-dihydro-2, 3-dimethyldibenz[b,e]oxepin-11-carboxylic acid obtained in Example 63 (Compound AB) in place of Compound A and 0.83 g of 2,6-diisopropylaniline in place of aniline to obtain 1.25 g of Compound 48.

Sources & evidence

ORD record: ord-6acfa61e3793443ab118e5f002d894c4
Source dataset: uspto-grants-1994_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05340807

Reaction notes

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