HCID 135405871, compound → HCID 135433152, compound

Participants

Reaction Conditions

Reaction Steps

19.6 g (44.9 mmol) of (R)-N-(5-nitrosalicylidene)-2-amino-1,1-di(2-methoxyphenyl)-1-propanol, 8.96 g (44.9 mmol) of cupric acetate, and 160 g of toluene were mixed in a flask and reacted at 80° C. for 1 hr under stirring. The reaction solution was cooled to 10° C. and blue-green chrystalls were deposited. Deposited crystals were collected by filtration, washed with 50 g of cold toluene, and dried at room temperature to give 19.1 g of a copper complex of (R) N-(5-nitrosalicylidene)-2-amino-1,1-di(2-methoxyphenyl)-1-propanol in a yield of 82.0%.

Provenance & Evidence