Pyridinium chloride → HCID 58078296, compound

HRID 1751337Notes

Reaction equation

HRID 1751337 reaction equation
C[O:2][C:3]1[CH:20]=[CH:19][C:18]2[C:17]3[C:12](=[CH:13][C:14]([O:21]C)=[CH:15][CH:16]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=1.Cl.N1C=CC=CC=1>O.CCOC(C)=O>[CH:4]1[C:5]2[C:6]3[C:11](=[CH:10][CH:9]=[CH:8][CH:7]=3)[C:12]3[C:17](=[CH:16][CH:15]=[C:14]([OH:21])[CH:13]=3)[C:18]=2[CH:19]=[CH:20][C:3]=1[OH:2]

Participants

5

Reactant 2

HCID 10176127Pyridinium chlorideHCID 16122314HCID 16122314, compound

Product 1

HCID 58078296HCID 58078296, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 8857Ethyl AcetateSolvent

Procedure

2,7-dimethoxytriphenylene (358 mg, 1.24 mmol) and pyridine hydrochloride (1.72 g, 14.9 mmol) were heated in a flask to 185° C. for 5 h. After cooling to rt, the remaining solid was diluted with H2O and EtOAc, separated, dried, and concentrated. Taken on crude.

Workup

  1. customseparated
  2. customdried
  3. concentrationconcentrated

Sources & evidence

ORD record
ord-f94daddfc6ec45bab2259e501889fc85
Source dataset
uspto-grants-2015_10
Patent number
US09156823B2

Reaction notes

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