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HRID1751911

反应详情

EQUATION

反应方程式

HRID 1751911 的结构方程式

REACTANTS

反应物

3
结构：[K+].[OH-]
HCID14797

Potassium hydroxide

HKO

结构：[Na+].[OH-]
HCID14798

Sodium Hydroxide

HNaO

结构：O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
HCID107526

未命名化合物

PRODUCTS

生成物

1
结构：O=C([O-])[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(=O)[O-].[K+].[K+]
HCID23624071

Dipotassium D-glucarate

C6H8K2O8

PROCEDURE

实验过程

The oxidation of D-glucose was carried out as in Examples 1 and 2. However, potassium hydroxide was substituted for sodium hydroxide in the neutralization process to give crude D-glucaric acid dipotassium salt (151.25 g, 70.4% based on pure dipotassium D-glucarate). The salt was precipitated from methanol as described to give an off white solid (145.75 g, 67.9% based on pure dipotassium D-glucarate).

WORKUP

后处理

  1. customto give crude D-glucaric acid dipotassium salt (151.25 g, 70.4% based on pure dipotassium D-glucarate)
  2. customThe salt was precipitated from methanol