Oxygen → N,N-diethyl-m-toluamide
Reaction equation
[O:1]=O.[CH:3]1[CH:8]=[CH:7][NH+:6]=[CH:5][CH:4]=1.[CH:9]1[CH:14]=C[NH+]=CC=1.[O-][Cr](O[Cr]([O-])(=O)=O)(=O)=O.[C:24]1([CH3:30])[CH:29]=[CH:28]C=C[CH:25]=1>>[CH3:4][CH2:5][N:6]([C:7]([C:8]1[CH:3]=[CH:28][CH:29]=[C:24]([CH3:30])[CH:25]=1)=[O:1])[CH2:14][CH3:9]Participants
Procedure
Glass coverslips (Thomas Scientific 6661 F52, 22×22 mm No. 1) were cleaned using an O2 plasma cleaner (Harrick PDC-32G) for 20 minutes at 100 mTorr. The DETA (United Chemical Technologies Inc. T2910KG) films were formed by the reaction of the cleaned glass surface with a 0.1% (v/v) mixture of the organosilane in freshly distilled toluene (Fisher T2904). The DETA coated coverslips were then heated to approximately QQ 100° C., rinsed with toluene, reheated to approximately 100° C., and then oven dried [28]. Surfaces were characterized by contact angle measurements using an optical contact angle goniometer (KSV Instruments, Cam 200) and by X-ray photoelectron spectroscopy (XPS) (Kratos Axis 165). XPS survey scans, as well as high-resolution N1s and C1s scans utilizing monochromatic Al Kα excitation were obtained [28].
Workup
- customfor 20 minutes
Sources & evidence
- ORD record
- ord-d9d0176895344090bdfe920e1c46d403
- Source dataset
- uspto-grants-2015_10
- Patent number
- US09163216B1
Reaction notes
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