2-Nitrotoluene → Azoxybenzene

HRID 1754019Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1754019
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)([O-:3])=O.C[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[N+:17]([O-])=O>>[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)(=[N:17][C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][CH:11]=1)[O-:3]

Komponenten

3

Edukt 2

HCID 69442-NitrotolueneHCID 7416Nitrobenzene2×

Produkt 1

HCID 10316Azoxybenzene

Versuchsvorschrift

The reduction reaction was carried out in the same manner as set forth in Example 6 except for using a mixture of 1.0 mmol of nitrobenzene and 1.0 mmol of o-methyl nitrobenzene instead of using nitrobenzene alone, and using 17 mg (the amount required for swelling of the reactant, i.e., the mixture, in 100%) of Polymer supported reagent-2, and thereby an azoxybenzene derivative of a symmetrical structure and an azoxybenzene derivative of an asymmetrical structure were obtained as a main product, respectively.

Aufarbeitung

  1. customThe reduction reaction

Quellen und Nachweise

ORD-Eintrag
ord-a16932aed11b409388fba55294fb8566
Quelldatensatz
uspto-grants-2015_10
Patentnummer
US09169200B2

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