HRID1755574

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Ce+4].[NH4+].[NH4+]

HCID180504

未命名化合物

结构：Cc1c(C)c2c(c(C)c1O)CCC(C)(C(=O)NCCOCCO)O2

HCID67263063

未命名化合物

PRODUCTS

生成物

结构：CC1=C(C)C(=O)C(CCC(C)(O)C(=O)NCCOCCO)=C(C)C1=O

HCID42599388

未命名化合物

PROCEDURE

实验过程

Oxidation as described in protocol B, using 98.1 mg (0.305 mmol) of 6-hydroxy-N-(2-(2-hydroxyethoxy)ethyl)-2,5,7,8-tetramethylchroman-2-carboxamide and 368 mg CAN (0.671 mmol) yielded 2-hydroxy-N-(2-(2-hydroxyethoxy)ethyl)-2-methyl-4-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)butanamide as a yellow oil.