Hydrogen Bromide → HCID 19392580, compound

HRID 1756067Notes

Reaction equation

HRID 1756067 reaction equation
[CH3:1][C:2]1[NH:10][C:5]2=[N:6][CH:7]=[CH:8][CH:9]=[C:4]2[C:3]=1[CH3:11].[N+:12]([C:15]1[CH:24]=[CH:23][CH:22]=[CH:21][C:16]=1[C:17](=[O:20])[CH2:18]Br)([O-:14])=[O:13].Br>>[CH3:1][C:2]1[N:10]=[C:5]2[N:6]([CH2:18][C:17]([C:16]3[CH:21]=[CH:22][CH:23]=[CH:24][C:15]=3[N+:12]([O-:14])=[O:13])=[O:20])[CH:7]=[CH:8][CH:9]=[C:4]2[C:3]=1[CH3:11]

Participants

4

Reactant 3

HCID 260Hydrogen BromideHCID 2440252-Bromo-2'-nitroacetophenoneHCID 125323872,3-Dimethyl-1H-pyrrolo[2,3-b]pyridine

Product 1

HCID 19392580HCID 19392580, compound

Procedure

The title compound was prepared on a 5 mmol scale from 2,3-dimethylpyrrolo[2,3-b]pyridine and o-nitrophenacyl bromide in the same manner as described in example 27 yielding 1.3 g (66%) pure hydrobromide as a yellow solid. Reprocessing of the motherliquor gave additional material.

Workup

  1. customReprocessing of the motherliquor gave additional material

Sources & evidence

ORD record
ord-67d34a9fc9d64f22900194526dd4ee80
Source dataset
uspto-grants-1995_08
Patent number
US05439917

Reaction notes

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