17-Bromoheptadec-6-en-1-ol → HCID 566286, compound

HRID 1756488Notes

Reaction equation

HRID 1756488 reaction equation
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH:12]=[CH:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][OH:19].[H][H]>C(O)C.[Pd]>[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][OH:19]

Participants

5

Reactant 2

HCID 5368882717-Bromoheptadec-6-en-1-olHCID 178418361HCID 178418361, compound

Product 1

HCID 566286HCID 566286, compoundYield 76.8%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

17-Bromoheptadec-6-en-l-ol (33.8 g) was subjected to hydrogenation in a Paar hydrogenation apparatus (50 psi initial hydrogen pressure), using ethanol as solvent and 10% palladium on charcoal as catalyst, to yield 17-bromoheptadecan-1-ol (26.1 g, 76% yield).

Sources & evidence

ORD record
ord-f853bea1018e491aac81b3a4c26462e0
Source dataset
uspto-grants-1995_08
Patent number
US05441731

Reaction notes

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