Methyl iodide → HCID 86748932, compound

HRID 1757260Notes

Reaction equation

HRID 1757260 reaction equation
[CH3:1]C(C)(C)C#C/C=C/C/C(=C\CCCCOC1C=CC=C(C2C=CSC=2)C=1)/CO.C(I)C.[CH3:33][C:34]([CH3:61])([CH3:60])[C:35]#[C:36]/[CH:37]=[CH:38]/[CH2:39]/[C:40](=[CH:43]\[CH2:44][CH2:45][CH2:46]/[CH:47]=[CH:48]/[C:49]1[CH:54]=[CH:53][CH:52]=[C:51]([C:55]2[CH:59]=[CH:58][S:57][CH:56]=2)[CH:50]=1)/[CH2:41][OH:42].CI>>[CH3:1][O:42][CH2:41]/[C:40](/[CH2:39]/[CH:38]=[CH:37]/[C:36]#[C:35][C:34]([CH3:61])([CH3:60])[CH3:33])=[CH:43]/[CH2:44][CH2:45][CH2:46]/[CH:47]=[CH:48]/[C:49]1[CH:50]=[C:51]([C:55]2[CH:59]=[CH:58][S:57][CH:56]=2)[CH:52]=[CH:53][CH:54]=1

Participants

5

Reactant 4

HCID 6328Methyl iodideHCID 6340IodoethaneHCID 15288594HCID 15288594, compoundHCID 15288595HCID 15288595, compound

Product 1

HCID 86748932HCID 86748932, compound

Procedure

The compounds of Examples 30 and 31 are obtained by carrying out the same reaction as in Example 29 except that (E,E)-2-(6,6-dimethyl-2-hepten-4-ynyl)-7-[3-(3-thienyl)phenoxy]-2-hepten-1-ol and/or ethyl iodide are used in place of (E,E,E)-2-(6,6-dimethyl-2-hepten-4-ynyl)-8-[3-(3-thienyl)phenyl]-2,7-octadien-1-ol and/or methyl iodide which is the raw material compound used in the above reaction.

Workup

  1. customused in the above reaction

Sources & evidence

ORD record
ord-64940ae553654151854ff0d43c1e7f0e
Source dataset
uspto-grants-1995_08
Patent number
US05444084

Reaction notes

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