1-Bromodecane → 1,2-Bis(decyloxy)-4-nitrobenzene

HRID 1757849Notes

Reaction equation

[N+:1]([C:4]1[CH:5]=[C:6]([OH:11])[C:7](=[CH:9][CH:10]=1)[OH:8])([O-:3])=[O:2].Br[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[CH2:13]([O:11][C:6]1[CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[CH:10]=[CH:9][C:7]=1[O:8][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]

Participants

Reactant 2

HCID 81731-Bromodecane

HCID 35051094-Nitrocatechol

Product 1

HCID 149801881,2-Bis(decyloxy)-4-nitrobenzene

Procedure

Using this procedure, the reaction of 4-nitrocatechol with 1-bromodecane gave 3,4-bis(decyloxy)nitrobenzene (mp 60°-61°, Anal. Calcd for C26H45NO4 : C, 71.68; H, 10.41; N, 3.22. Found: C, 71.63; H, 10.55; N, 3.21.

Sources & evidence

ORD record: ord-b5ef6240bd6f4d0382015f5a9f6f85a3
Source dataset: uspto-grants-1995_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05446189

Reaction notes

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