Bisphenol A diglycidyl ether → 2,2-bis[4-{3-[4-(N-butylacetamido)-2,2,6,6-tetramethylpiperidino]-2-hydroxypropoxy}phenyl]propane

HRID 1758195Notes

Reaction equation

HRID 1758195 reaction equation
[CH2:1]([N:5]([CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[NH:12][C:11]([CH3:18])([CH3:17])[CH2:10]1)[C:6](=[O:8])[CH3:7])[CH2:2][CH2:3][CH3:4].[O:19]1[CH2:43][CH:20]1[CH2:21][O:22][C:23]1[CH:28]=[CH:27][C:26]([C:29]([C:32]2[CH:37]=[CH:36][C:35]([O:38][CH2:39][CH:40]3[O:42][CH2:41]3)=[CH:34][CH:33]=2)([CH3:31])[CH3:30])=[CH:25][CH:24]=1>C(O)(C)(C)C>[CH2:1]([N:5]([CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[N:12]([CH2:41][CH:40]([OH:42])[CH2:39][O:38][C:35]2[CH:36]=[CH:37][C:32]([C:29]([C:26]3[CH:27]=[CH:28][C:23]([O:22][CH2:21][CH:20]([OH:19])[CH2:43][N:12]4[C:13]([CH3:15])([CH3:16])[CH2:14][CH:9]([N:5]([CH2:1][CH2:2][CH2:3][CH3:4])[C:6](=[O:8])[CH3:7])[CH2:10][C:11]4([CH3:17])[CH3:18])=[CH:24][CH:25]=3)([CH3:31])[CH3:30])=[CH:33][CH:34]=2)[C:11]([CH3:17])([CH3:18])[CH2:10]1)[C:6](=[O:8])[CH3:7])[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 2286Bisphenol A diglycidyl etherHCID 212252644-(N-butylacetamido)-2,2,6,6-tetramethylpiperidine

Product 1

HCID 205105822,2-bis[4-{3-[4-(N-butylacetamido)-2,2,6,6-tetramethylpiperidino]-2-hydroxypropoxy}phenyl]propane

Reagents, catalysts & solvents 1

HCID 6386tert-ButanolSolvent

Procedure

To 20 ml of t-butanol were added 5.0 g of 4-(N-butylacetamido)-2,2,6,6-tetramethylpiperidine and 2.8 g of 2,2-bis[p-(2,3-epoxypropoxy)phenyl]propane, and the mixture was reacted following the procedure described in Example 1 to give the desired Compound No. 234 in the form of a white vitreous mass. The compound had an Rf value of 0.54 on thin-layer chromatography on silica gel developed with a 20:1 by volume mixture of ethyl acetate and triethylamine.

Workup

  1. customthe mixture was reacted

Sources & evidence

ORD record
ord-4e47a549f07e4d768e76bc29d4bec11e
Source dataset
uspto-grants-1983_02
Patent number
US04371644

Reaction notes

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