反应详情

5-Benzylthio-2-(1H-tetrazole-5-ylmethyl)-2H-tetrazole, 175 mg., prepared as described above under part C, was dissolved in 40 ml. of distilled DMF and reduced at the mercury pool cathode (14 cm2Hg pool) with a platinium wire anode. The electrodes were separated by a glass frit. The electrolyte was tetraethylammonium perchlorate, 0.1 M in the DMF solution of the substrate. The electrolysis was carried out at -2.7 to -2.85 volts for 500 seconds and at -2.80 v. for about 630 seconds.

1. custom, prepared
2. dissolutionwas dissolved in 40 ml
3. customThe electrodes were separated by a glass frit
4. waitfor about 630 seconds