Sodium Iodide → HCID 178468131, compound

HRID 1759163Notes

Reaction equation

HRID 1759163 reaction equation
[C:1]([CH2:4][CH2:5][PH:6](=[O:9])[O:7]C)(=[O:3])[CH3:2].[I-].[Na+:11]>CC(CC)=O>[C:1]([CH2:4][CH2:5][PH:6](=[O:7])[O-:9])(=[O:3])[CH3:2].[Na+:11]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 178502929HCID 178502929, compound

Product 1

HCID 178468131HCID 178468131, compound

Reagents, catalysts & solvents 1

HCID 6569Methyl Ethyl KetoneSolvent

Procedure

Methyl acetylethylphosphinate (6 g)was reacted with sodium iodide (6.0 g) in ethyl methyl ketone (50 ml) in the same manner as in Example 12. The solution was stirred and refluxed 1.25 hours, cooled and the product filtered off and washed with a little ethyl methyl ketone and dried in vacuo (5.3 g). Decomposes 192°-4°.

Workup

  1. temperaturerefluxed 1.25 hours
  2. temperaturecooled
  3. filtrationthe product filtered off
  4. washwashed with a little ethyl methyl ketone
  5. customdried in vacuo (5.3 g)
  6. customDecomposes 192°-4°

Sources & evidence

ORD record
ord-63a9b995678a4d39b5cfe701e9e19c3c
Source dataset
uspto-grants-1982_07
Patent number
US04339443

Reaction notes

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