1-Butyl-4-butylamino-3,5-dipropyl-1,2,4-triazolium chloride → 1-Butyl-4-butylamino-3,5-dipropyl-1,2,4-triazolium (1,1-dimethyloxyethyl)methylphosphinate

HRID 1759176Notes

Reaction equation

HRID 1759176 reaction equation
[CH3:1][O:2][C:3]([P:7]([CH3:10])(=[O:9])[O-:8])([O:5][CH3:6])[CH3:4].[Na+].[Cl-].[CH2:13]([N+:17]1[N:18]=[C:19]([CH2:30][CH2:31][CH3:32])[N:20]([NH:25][CH2:26][CH2:27][CH2:28][CH3:29])[C:21]=1[CH2:22][CH2:23][CH3:24])[CH2:14][CH2:15][CH3:16]>>[CH3:1][O:2][C:3]([P:7]([CH3:10])(=[O:8])[O-:9])([O:5][CH3:6])[CH3:4].[CH2:13]([N+:17]1[N:18]=[C:19]([CH2:30][CH2:31][CH3:32])[N:20]([NH:25][CH2:26][CH2:27][CH2:28][CH3:29])[C:21]=1[CH2:22][CH2:23][CH3:24])[CH2:14][CH2:15][CH3:16]

Participants

3

Reactant 2

HCID 205322811-Butyl-4-butylamino-3,5-dipropyl-1,2,4-triazolium chlorideHCID 86738481HCID 86738481, compound

Product 1

HCID 867384921-Butyl-4-butylamino-3,5-dipropyl-1,2,4-triazolium (1,1-dimethyloxyethyl)methylphosphinateYield 76.5%

Procedure

By the procedure of Example 53 the product of Example 18 (3.8 g) and 1-butyl-4-butylamino-3,5-dipropyl-1,2,4-triazolium chloride (6.0 g) were mixed and the reaction worked up to give the rquired salt as a pale yellow oil (6.5 g). The nmr spectrum was in agreement with the required structure.

Sources & evidence

ORD record
ord-f96dec6ecd4e4a19a13591c8b9ef8657
Source dataset
uspto-grants-1982_07
Patent number
US04339443

Reaction notes

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