Pyrrolidine → HCID 12919203, compound

HRID 1759179Notes

Reaction equation

HRID 1759179 reaction equation
[O:1]1[CH2:15][CH:2]1[CH2:3][O:4]/[N:5]=[C:6]1\[CH2:7][CH2:8][CH2:9][C:10]2[S:11][CH:12]=[CH:13][C:14]\1=2.[NH:16]1[CH2:20][CH2:19][CH2:18][CH2:17]1.C([O-])(=O)C([O-])=O>>[OH:1][CH:2]([CH2:15][N:16]1[CH2:20][CH2:19][CH2:18][CH2:17]1)[CH2:3][O:4]/[N:5]=[C:6]1\[CH2:7][CH2:8][CH2:9][C:10]2[S:11][CH:12]=[CH:13][C:14]\1=2

Participants

4

Reactant 3

HCID 31268PyrrolidineHCID 71081OxalateHCID 12919162HCID 12919162, compound

Product 1

HCID 12919203HCID 12919203, compoundYield 77.5%

Procedure

This compound is prepared by the procedure described in Example 1 by condensing E-4-(2,3-epoxypropoxy)imino-4,5,6,7-tetrahydrobenzo[b]thiophene with pyrrolidine. Oxalate: white crystals; m.p. 136° C. (recrystallised from isopropyl alcohol); yield: 77.5% of theory.

Workup

  1. customThis compound is prepared by the procedure
  2. customm.p. 136° C. (recrystallised from isopropyl alcohol)

Sources & evidence

ORD record
ord-d912f70357cc42e382afe9112da5201d
Source dataset
uspto-grants-1982_07
Patent number
US04339450

Reaction notes

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