Methyl (methylsulfinyl)methyl sulfide → 1-Amino-1-[2-methyl-5-benzo(b)furanyl]-2-methylsulphinyl-2-methylthioethylene
Reaction equation
[CH3:1][C:2]1[O:6][C:5]2[CH:7]=[CH:8][C:9]([C:11]#[N:12])=[CH:10][C:4]=2[CH:3]=1.[CH3:13][S:14][CH2:15][S:16]([CH3:18])=[O:17]>>[NH2:12][C:11]([C:9]1[CH:8]=[CH:7][C:5]2[O:6][C:2]([CH3:1])=[CH:3][C:4]=2[CH:10]=1)=[C:15]([S:16]([CH3:18])=[O:17])[S:14][CH3:13]Participants
3
Procedure
2-Methyl-5-cyanobenzo(b)furan (17.25 g., 0.11 mole) was treated with methyl methylthiomethyl sulphoxide as described in Example 8, Part B, to yield 1-amino-1-[2-methyl-5-benzo(b)furanyl]-2-methylsulphinyl-2-methylthioethylene (12.4 g.), m.p. 185°-186° C.
Sources & evidence
- ORD record
- ord-b6494a19413b48358a396b7fef39c4b4
- Source dataset
- uspto-grants-1982_07
- Patent number
- US04341792
Reaction notes
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