4-(Methylthio)aniline → 4-(Methylsulfinyl)aniline
Reaction equation
[CH3:1][S:2][C:3]1[CH:9]=[CH:8][C:6]([NH2:7])=[CH:5][CH:4]=1.ClC1C=CC=C(C(OO)=[O:18])C=1>>[CH3:1][S:2]([C:3]1[CH:9]=[CH:8][C:6]([NH2:7])=[CH:5][CH:4]=1)=[O:18]Participants
3
Procedure
Following a similar procedure to that described in reference example 1, but starting from 4-methylthioaniline and using 1 equivalent of m-chloroperbenzoic acid, the title compound of the example was obtained as a white solid (80% yield).
Sources & evidence
- ORD record
- ord-7a6df421e9ce4d1abb8fadb5e9e470c0
- Source dataset
- uspto-grants-2005_01
- Patent number
- US06838476B1
Reaction notes
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