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HRID1760894

反应详情

EQUATION

反应方程式

HRID 1760894 的结构方程式

REACTANTS

反应物

2
结构：O=S(Cl)Cl
HCID24386

Thionyl chloride

Cl2OS

结构：OCc1cc(OCc2ccccc2)c(OCc2ccccc2)c(OCc2ccccc2)c1
HCID11407668

[3,4,5-Tris(benzyloxy)phenyl]methanol

C28H26O4

PRODUCTS

生成物

1
结构：ClCc1cc(OCc2ccccc2)c(OCc2ccccc2)c(OCc2ccccc2)c1
HCID22593238

1,1',1''-{[5-(Chloromethyl)benzene-1,2,3-triyl]tris(oxymethylene)}tribenzene

C28H25ClO3

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCOCC
溶剂HCID3283

Diethyl Ether

C4H10O

PROCEDURE

实验过程

40.0 g (0.33 mol) of thionyl chloride are added dropwise at room temperature to a suspension of 12.0 g (0.028 mol) of 3,4,5-trisbenzyloxybenzyl alcohol in 100 ml of diethyl ether. Heating is then carried out at reflux for 2 hours, resulting in a clear solution. After removal of excess thionyl chloride and solvent, the residue is recrystallised from isopropanol/hexane.

WORKUP

后处理

  1. temperatureHeating
  2. temperatureat reflux for 2 hours
  3. customresulting in a clear solution
  4. customAfter removal of excess thionyl chloride and solvent
  5. customthe residue is recrystallised from isopropanol/hexane