m-Chloroperbenzoic acid → HCID 21242384, compound

HRID 1761728Notes

Reaction equation

HRID 1761728 reaction equation
[CH3:1][C:2]([O:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])([CH3:5])[CH:3]=[CH2:4].ClC1C=CC=C(C(OO)=[O:31])C=1>C(Cl)Cl>[CH2:7]([O:6][C:2]([CH:3]1[CH2:4][O:31]1)([CH3:1])[CH3:5])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acid2×HCID 21242397HCID 21242397, compound

Product 1

HCID 21242384HCID 21242384, compoundYield 93.8%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

A mixture of 36.5g of 1-[(1,1-dimethyl-2-propenyl)oxy]hexadecane, 23.92 g of m-chloroperbenzoic acid and 225 ml of methylene chloride was stirred overnight. A 7 g portion of m-chloroperbenzoic acid was added, then the mixture was stored in a chill room for 56 hours. This mixture was filtered. The filtrate was washed with dilute aqueous sodium bisulfite, then saturated aqueous sodium bicarbonate, dried and the solvent removed, giving 36 g of the desired compound.

Workup

  1. waitthe mixture was stored in a chill room for 56 hours
  2. filtrationThis mixture was filtered
  3. washThe filtrate was washed with dilute aqueous sodium bisulfite
  4. dry with materialsaturated aqueous sodium bicarbonate, dried
  5. customthe solvent removed

Sources & evidence

ORD record
ord-d69c58e1341d47cca9bfd602d66cbeaf
Source dataset
uspto-grants-1989_05
Patent number
US04827011

Reaction notes

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